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Wood Department of Chemistry TRAINING MANUAL (POLICE AND MAINTENANCE) INTRODUCTION: We come into contact with chemicals every day. Some of these might not be recognized as such. They include things like oven cleaners, drain openers and emergency flares. These are much more hazardous than many chemicals found in the laboratory. Other materials found in the home are routinely used in the laboratory. Sodium bicarbonate (bicarb), sodium chloride (table salt), sucrose (sugar) and sodium hypochlorite (bleach) are examples of these. Thus, it may be seen that many chemicals are essential and beneficial substances. However, they must be used properly. One of the major operating principles in the safe handling of hazardous chemicals is to remember to use common sense in uncommon situations. I. LABELS All chemicals in the College of Natural Science and Mathematics must be labeled appropriately. The label on the chemical will either be one generated In House by faculty or student, or it will be one affixed by a supplier. A. In House labels must contain key signal words on hazardous materials. You should become familiar with the dangers denoted by these words: 1. Corrosive: A liquid or solid that causes visible destruction or irreversible alterations in human skin tissue at the site of contact. Common examples: concentrated acids, concentrated bases. 2. Poison Class A: Denotes the most poisonous rating. 3. Flammable: A substance capable of being ignited. 4. Explosive Class A: Denotes the most dangerous class. 5. Oxidizer: This substance initiates or promotes combustion in other materials. 6. Peroxide: A substance which may decompose by itself to release large amounts of energy. May initiate a reaction in other substances. 7. Lachrymator: A substance which causes intense irritation of mucous membranes and eyes. 8. Radioactive Material: Any material which spontaneously emits ionizing radiation. 9. Biohazard: A viable microorganism, or its toxin, which causes or may cause human disease. Pathogen. 10. Carcinogenic: Human exposure to this substance may result in the development of cancer. 11. Mutagenic: Human exposure to this substance may produce heritable genetic effects. 12. Teratogenic: Human exposure to this substance may produce non-heritable birth defects in offspring. B. Most of the chemicals obtained from chemical supply houses will have affixed the National Fire Protection Association 704 (NFPA 704) system of protective labeling. The chemical will have a color coded diamond on the container. The diamond is divided into four sections. Three of the four sections have a number in them. This number indicates the severity of the hazard. The numbers rang from 0 to 4, with 4 the most hazardous. The left section of the diamond is blue in color and informs the user of the health hazard of the substance. The top section of the diamond is red. This indicates the flammability hazard. The right section of the diamond is yellow and indicates the reactivity hazard. The bottom section of the diamond is white and contains special warning messages about the substance. Examples: w (react to water) oxy (oxidizer) p (polymerization hazard) HEALTH RATINGS: 4. Deadly Materials which on very short exposure could cause death or major residual injury even though prompt medical treatment was given. Protective clothing and respiratory equipment with independent air supply must be used in an area contaminated with this material. Caution!! This material may penetrate rubber clothing. 3. Extreme Danger Material which on short exposure could cause serious temporary or residual injury even though prompt medical treatment was given. Protective clothing and respiratory equipment with an independent air supply must be used in an area contaminated with this material. 2. Hazardous Material which on intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical treatment is given. Protective clothing and respiratory equipment with an independent air supply should be used in an area contaminated with this material. 1. Slightly Hazardous Material which upon exposure would cause irritation but only minor residual injury even if no treatment is given. May require protective clothing and approved canister type gas mask in an area contaminated with this material. 0. Non Hazardous Material which on exposure under fire conditions would offer no hazard beyond that of ordinary combustible material. FLAMMABLE RATINGS: Susceptibility of materials to burning. 4. Extremely Flammable Materials which will rapidly or completely vaporize at atmospheric pressure and normal room temperature and which will burn rapidly. Materials which have a flash point below 73şF and a boiling point below 100şF. 3. Very Flammable Materials which can be ignited under atmospheric pressure and ambient temperature. Materials which have a flash point below 100şF and have a boiling point below 100şF. These materials usually do not burn explosively. This class includes pyrophoric solids, such as white phosphorus, that spontaneously ignite in air. 2. Flammable Materials that must be moderately heated or exposed to relatively high ambient temperature before ignition can occur. Materials in this rating would not form a hazardous atmosphere with air. This class includes liquids with a flash point above 100şF, but not exceeding 200şF. 1. Combustible Materials that must be preheated before ignition can occur. Materials in this rating require considerable preheating before ignition and combustion can occur. Materials have a flash point above 200şF. These will burn in air when exposed to a temperature of 1500şF for a period of 5 minutes or less. 0. Non Flammable Materials will not burn. Ignition in air will not occur when these are exposed to a temperature of 1500şF for a period of 5 minutes. REACTIVITY RATINGS: The ratings are ranked according to ease of initiation of reaction, rate of reaction and quantity of energy released. 4. Extremely Explosive These materials are readily capable of detonation or of explosive decomposition or reaction at room temperature and atmospheric pressure. They are sensitive to mechanical or localized thermal shock at room temperatures and pressure. 3. Explosive These materials are capable of detonation or explosive reaction but require a strong initiating source or which must be heated under confinement before initiation. This class also includes substances which react explosively with water. These include materials which are sensitive to thermal shock or mechanical shock at elevated temperatures and pressures. 2. Extremely Reactive These materials are normally unstable and readily undergo violent chemical change but do not detonate. These are materials which undergo a rapid release of energy at room temperature and atmospheric pressure. It also includes materials which react violently with water. 1. Reactive These materials are normally stable but can become unstable at elevated temperatures and pressures. 0. Stable These materials are normally inert even upon exposure to fire. SPECIFIC HAZARD: oxy Oxidizer This substance initiates or promotes combustion in other materials. alk Alkali This material is caustic. It will severely damage skin, eyes, etc. cor Corrosive This material will reactive with metal surfaces. This is also caustic. w Use no water Do not allow this material to come into contact with water. It will react violently with water. II. CHEMICAL SPILLS A. CHEMICAL SPILLS ON THE BODY Immediate action must be undertaken when chemicals or reagents are spilled on clothing or the skin. If the substance contacts the clothes, the best first action the person can take is to remove the contaminated article of clothing. The area of skin beneath the area of contamination should then be flushed with running water. The rinse should continue for approximately 20 minutes. Caution: Alkali material will cause much more damage to tissue than an acid of comparable concentration. If the area of contamination is large, the person should use the body shower. While under the stream of water from the shower, the person should remove the articles of clothing affected. B. CHEMICAL SPLASHES IN THE EYE The major point here: GET TO THE EYE WASH STATION OR ANY SOURCE OF WATER (WHETHER IT IS DRINKING FOUNTAIN OR SINK) AND WASH THE EYE THOROUGHLY. The eye must be flushed for at least 20 minutes with flowing water. The person should then be transported immediately to the hospital emergency room. C. SPILLS ON THE FLOOR, ETC. The material should be contained using the Spill Control Kits found in the chemical stockroom or the various prep rooms. If this is not available, the absorbent used in the power plant will do. After the spill is contained, the Chemical Hygiene Officer of the Dean of CNSM should be contacted. III. ENCOUNTERING AN UNKNOWN LIQUID If you encounter an unknown liquid spilled in the area you are in, it may be of value to determine if it is an organic liquid. This would help in assessing the danger of fire in the area. In general, organic liquids will have an odor like one of the following: 1. Gasoline, lighter fluid or kerosene. 2. Fingernail polish remover. 3. Paint thinner. 4. Oil base paint. 5. “Starter” fluid. 6. Somewhat like ammonia. The above odors may indicate the presence of a substance with a flammability rating of at least 2. The appropriate precautions should be taken. IV. MSDS If needed, a Material Safety Data Sheet (MSDS) can be obtained for materials present in the College of Natural Science and Mathematics. These can be obtained in the chemical stockroom or from the Campus Safety Office in the Administrative Annex. Once the MSDS for a particular material is obtained, you should be aware that the MSDS outlines only minimum precautions for the safe handling of a chemical. It also documents fire and explosion hazards, spill or leak procedures, special protection information and special precautions. The MSDS should also contain first aid procedures. When an MSDS fails to mention a particular detrimental health effect, it should not be assumed that the substance is hazard free. 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